potassium titanium oxide phosphate | 12690-20-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属含氧阴离子化合物
• 英文名称: potassium titanium oxide phosphate
• 英文别名: potassium titanyl phosphate；Potassium titanium oxide phosphate (KTiO(PO4))；potassium;oxygen(2-);titanium(4+);phosphate
• CAS: 12690-20-9
• 化学式: K*O*O₄P*Ti
• 分子量: 197.949
• InChiKey: WYOHGPUPVHHUGO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -5.94
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  potassium dihydrogenphosphate 、 dioxide titanium 以 乙醇 为溶剂， 反应 15.0h， 生成 potassium titanium oxide phosphate
  参考文献：
  名称：

  KTiOPO4 as a novel anode material for sodium-ion batteries

  摘要：

  KTiOPO4 (KTP) microblocks, which were prepared using a simple solid state method, have been used as novel anode materials for sodium ion batteries (SIBs). The as-prepared KTP microblocks with size distribution of 300-500 nm delivered high performance of electrochemical storage of sodium, such as an initial charge capacity of 108.7 mAh g(-1) at 200 mAg(-1) with almost no capacity loss in 1000 cycles, and good rate capability of 80.3 mAh g(-1) even at the current density of 1000 mAg(-1). Ex situ XPS and in situ XRD showed an irreversible phase reaction mechanism during the insertion/extraction of Na+. Dendrite formation at lower potential could be suppressed at the average potential of 1.3 V. This work indicated that KTP microblocks are low-cost and safe anode materials for SIBs. (C) 2018 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2018.04.290

文献信息

• Rangan, K. Kasthuri; Prasad, B. Raghavendra; Subramanian, Inorganic Chemistry, 1993, vol. 32, # 20, p. 4291 - 4293
  作者：Rangan, K. Kasthuri、Prasad, B. Raghavendra、Subramanian、Gopalakrishnan

  DOI：——

  日期：——