[BrMo.tplbond.C.CH2Ph(P(OMe)3)2(η-C5H5)][BF4] | 88666-57-3

• 英文名称: [BrMo.tplbond.C.CH2Ph(P(OMe)3)2(η-C5H5)][BF4]
• CAS: 88666-57-3
• 化学式: BF₄*C₁₉H₃₀BrMoO₆P₂
• 分子量: 679.04
• InChiKey: USLFGWZGUSWXNQ-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  [BrMo.tplbond.C.CH2Ph(P(OMe)3)2(η-C5H5)][BF4] 在 Na amalgam 作用下， 以 四氢呋喃 为溶剂， 生成 {Mo(CCH2Ph)(P(OMe)3)2(η-C5H5)}
  参考文献：
  名称：

  The formation of vinylidene molybdenum complexes and their transformation into mononuclear carbyne complexes; X-ray crystal structure of [Mo{CCHPh}Br{P(OMe)₃}₂(η-C₅H₅)]

  摘要：

  Reaction of [Mo(PhC2Br){P(OMe)3}2(η-C5H5)][BF4] with K[BHBu3s] or Li2Cu2Me4 gives respectively [Mo{CCHPh}Br{P(OMe)3}2(η-C5H5)] and [MoC·CMe2Ph{P(OMe)3}2(η-C5H5)]; the bromovinylidene react with K[BHBu3s] to give [MoC·CH2Ph{P(OMe)3}2(η-C5H5)] in good yield and with HBF4–Et2O to give [BrMoC·CH2Ph{P(OMe)3}2(η-C5H5)][BF4], which is reduced by Na–Hg to [MoC·CH2Ph{P(OMe)3}2-(η-C5H5)].

  DOI：

  10.1039/c39830000673
• 作为产物：
  描述：

  四氟硼酸-二乙醚络合物 、 以 乙醚 为溶剂， 生成 [BrMo.tplbond.C.CH2Ph(P(OMe)3)2(η-C5H5)][BF4]
  参考文献：
  名称：

  The formation of vinylidene molybdenum complexes and their transformation into mononuclear carbyne complexes; X-ray crystal structure of [Mo{CCHPh}Br{P(OMe)₃}₂(η-C₅H₅)]

  摘要：

  Reaction of [Mo(PhC2Br){P(OMe)3}2(η-C5H5)][BF4] with K[BHBu3s] or Li2Cu2Me4 gives respectively [Mo{CCHPh}Br{P(OMe)3}2(η-C5H5)] and [MoC·CMe2Ph{P(OMe)3}2(η-C5H5)]; the bromovinylidene react with K[BHBu3s] to give [MoC·CH2Ph{P(OMe)3}2(η-C5H5)] in good yield and with HBF4–Et2O to give [BrMoC·CH2Ph{P(OMe)3}2(η-C5H5)][BF4], which is reduced by Na–Hg to [MoC·CH2Ph{P(OMe)3}2-(η-C5H5)].

  DOI：

  10.1039/c39830000673