Acetic acid (3R,4S,5R,6R)-3-acetoxy-6-acetoxymethyl-2-(2,3-bis-hexadecyloxy-propoxy)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester | 86342-10-1

• 英文名称: Acetic acid (3R,4S,5R,6R)-3-acetoxy-6-acetoxymethyl-2-(2,3-bis-hexadecyloxy-propoxy)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester
• CAS: 86342-10-1
• 化学式: C₆₁H₁₀₆O₂₀
• 分子量: 1159.5
• InChiKey: NXFDDRCSEZDPPZ-WDSNHHLRSA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (3R,4S,5R,6R)-3-acetoxy-6-acetoxymethyl-2-(2,3-bis-hexadecyloxy-propoxy)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester 在 sodium methylate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以67%的产率得到(2R,3R,4S,5S,6R)-2-[(2R,3S,4R,5R)-6-(2,3-Bis-hexadecyloxy-propoxy)-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy]-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol
  参考文献：
  名称：

  An efficient and stereoselective synthesis of 1,2-0-dialkyl-3-0-β-d-dlycosyl-sn-glycerols

  摘要：

  DOI：

  10.1016/s0040-4039(00)81621-4
• 作为产物：
  描述：

  1,2-O-dihexadecyl-sn-glycerol 、 2,3,6,2',3',4',6'-hepta-O-acetyl-α-D-maltosyl bromide 在 碘 、 silver(l) oxide 作用下， 以 苯 为溶剂， 反应 20.0h， 以71%的产率得到Acetic acid (3R,4S,5R,6R)-3-acetoxy-6-acetoxymethyl-2-(2,3-bis-hexadecyloxy-propoxy)-5-((2R,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-4-yl ester
  参考文献：
  名称：

  An efficient and stereoselective synthesis of 1,2-0-dialkyl-3-0-β-d-dlycosyl-sn-glycerols

  摘要：

  DOI：

  10.1016/s0040-4039(00)81621-4