Formation of dinitrogen complexes by nucleophilic attack at a singly bent aryldiazenido ligand (N2R) in [(η5-MeC5H4)Mn(CO)2(N2R)][BF4] and [(η5-C5H5)Re(CO)2(N2R)][BF4]
摘要:
新的芳基重氮络合物[(η5-MeC5H4)Mn(CO)2(N2R)][BF4](R =o-CF3C6H4, o-FC6H4, or Ph)和[(η5-C5H5)Re(CO)2(N2R)][BF4](R =o-CF3C6H4)与亲核试剂如I-、Cl-、Br-、CN-或SCN-反应,生成二氮络合物[(η5-MeC5H4)Mn(CO)2N2]和[(η5-C5H5)Re(CO)2N2]。