boron dicarbonyl | 145144-01-0

• 英文名称: boron dicarbonyl
• CAS: 145144-01-0
• 化学式: C₂BO₂
• 分子量: 66.8318
• InChiKey: RIUDAWBVSBXGBD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  一氧化碳 、 硼烷 以 gaseous matrix 为溶剂， 生成 boron monocarbonyl 、 diboron dicarbonyl 、 boron dicarbonyl
  参考文献：
  名称：

  Reaction of boron atoms with carbon monoxide: matrix infrared spectra of BCO, (BCO)2, and B(CO)2

  摘要：

  Infrared spectra were obtained for Ar/CO samples codeposited with laser ablated boron atoms on a 12 +/- 1 K salt window. BCO was identified as the primary reaction product, based on isotopic substitution at all atomic positions and ab initio structure and frequency calculations. The dicarbonyl, B(CO)2, and the linear dimer, (BCO)2, were also identified from the infrared spectra. A higher cluster species containing bridging carbonyls appeared on annealing and was stable until the matrix sublimed away.

  DOI：

  10.1021/j100204a020