| 140219-42-7

• CAS: 140219-42-7
• 化学式: C₃₀H₄₁MoN₅S₃Si₃
• 分子量: 748.084
• InChiKey: MLHNZFPTKPLGOV-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  四氟硼酸-二乙醚络合物 、 以 二氯甲烷 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3]

  摘要：

  The reaction of [Mo2Cl4(mu-S2)(mu-2-SC5H3NH-3-SiMe3)(2-SC5H3N-3-SiMe3)2] with phenylhydrazine yields [Mo(NNPh)(2-SC5H3N-3-SiMe3)3] (1). Complex 1 adopts a pentagonal bipyramidal geometry with the phenyldiazenido group occupying an axial position. The structural parameters exhibited by 1 are similar to those of other members of the class of seven coordinate Mo-hydrazido and Mo-diazenido species. Crystal data for C30H41N5Si3S3Mo (1): monoclinic space group P2(1)n, a = 11.600(2), b = 14.880(3), c = 21.681(3) angstrom, beta = 90.46(1)degrees, V = 3242.2(12) angstrom 3, Z = 4; 5690 reflections, R = 0.049.

  DOI：

  10.1016/s0020-1693(00)80251-0
• 作为产物：
  描述：

  、 苯肼 以 二氯甲烷 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3]

  摘要：

  The reaction of [Mo2Cl4(mu-S2)(mu-2-SC5H3NH-3-SiMe3)(2-SC5H3N-3-SiMe3)2] with phenylhydrazine yields [Mo(NNPh)(2-SC5H3N-3-SiMe3)3] (1). Complex 1 adopts a pentagonal bipyramidal geometry with the phenyldiazenido group occupying an axial position. The structural parameters exhibited by 1 are similar to those of other members of the class of seven coordinate Mo-hydrazido and Mo-diazenido species. Crystal data for C30H41N5Si3S3Mo (1): monoclinic space group P2(1)n, a = 11.600(2), b = 14.880(3), c = 21.681(3) angstrom, beta = 90.46(1)degrees, V = 3242.2(12) angstrom 3, Z = 4; 5690 reflections, R = 0.049.

  DOI：

  10.1016/s0020-1693(00)80251-0