cis-trans-(4,4'-dimethylbipyridine)carbonyl(methylisocyanide)bis(triethylphosphite)manganese hexafluorophosphate | 149421-19-2

• 英文名称: cis-trans-(4,4'-dimethylbipyridine)carbonyl(methylisocyanide)bis(triethylphosphite)manganese hexafluorophosphate
• CAS: 149421-19-2
• 化学式: C₂₇H₄₅MnN₃O₇P₂*F₆P
• 分子量: 785.52
• InChiKey: SESVGQTWXMMENY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 cis-trans-(4,4'-dimethylbipyridine)carbonyl(cyano)bis(triethylphosphite)manganese 在 碘甲烷 作用下， 以 四氢呋喃 为溶剂， 生成 cis-trans-(4,4'-dimethylbipyridine)carbonyl(methylisocyanide)bis(triethylphosphite)manganese hexafluorophosphate
  参考文献：
  名称：

  Synthesis of new neutral and cationic monocarbonyl complexes of manganese with bipyridine ligands

  摘要：

  The irradiation with UV light at - 12-degrees-C of the neutral complexes fac-[Mn(CN)(CO)3(NN)] (NN = bipyridine, or 4,4'-dimethylbipyridine) in the presence of L = P(OR)3 (R = Me, Et or Ph) in CH2Cl2 gave the neutral monocarbonyls of formula trans-[Mn(CN)(CO)(NN)L2]. These complexes reacted with MeI and KPF6 in THF at room temperature to give the new cationic methyl-isocyanide monocarbonyls trans-[Mn(CNMe)(CO)(NN)L2]PF6.

  DOI：

  10.1016/0022-328x(93)83177-w