| 182571-25-1

• CAS: 182571-25-1
• 化学式: C₁₃H₁₉Cl₂O₃P₂RhRu
• 分子量: 560.121
• InChiKey: COUZVFSRBGLJHL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  、 一氧化碳 以 not given 为溶剂， 生成
  参考文献：
  名称：

  In situ spectroscopic evidence for facile, carbon monoxide mediated, reversible cleavage of neutral heterobimetallic rhodium–ruthenium complexes into ionic mononuclear complexes

  摘要：

  In situ IR and NMR spectroscopic evidence is presented for the facile and reversible cleavage of ligand-bridged metal-metal bonds in heterobimetallic Rh-Ru complexes of the type [(C(5)R(5))Ru(mu-CO)(2)(mu-LL)RhX(2)] [R = H, Me; LL = Ph(2)PCH(2)PPh(2) (dppm), Me(2)PCH(2)PMe(2) (dmpm) or Ph(2)PC(=CH2)PPh(2) (dppee); X = Cl, I] upon reaction with carbon monoxide under mild conditions to form [Ru(C(5)R(5))(CO)(2)(eta(1)-LL)](+) and [RhX(2)(CO)(2)](-); an intermediate species in the cleavage process, [(C5H5)(CO)(2)Ru(mu-Me(2)PCH(2)PMe(2))Rh(CO)Cl-2], is detected by NMR spectroscopy.

  DOI：

  10.1039/cc9960002061