摘要:
The tetranuclear cluster [Zn(2)L(mu-OH)](2)[ClO4](2) . 2H(2)O (L = dianion of the condensation product of 1,3-diaminopropane and 2,6-diformyl-4-methylthiophenol) shows two unique dinuclear Zn-II units linked by two Ir-hydroxy bridges; the structure of the Cu-II complex [Cu(2)L(HOMe)(2)](NO3)]PF6 shows square-pyramidal coordination at the Cu centres with two thiolate bridges and two terminal N-donors, with a Cu ... Cu separation of 3.264(2) Angstrom.