(η(4)-1,5-cyclooctadiene)(thioacetylacetonato)iridium | 169135-99-3

• 英文名称: (η(4)-1,5-cyclooctadiene)(thioacetylacetonato)iridium
• CAS: 169135-99-3
• 化学式: C₁₃H₁₉IrOS
• 分子量: 415.579
• InChiKey: CBERQCCPCJDADX-GCOBPYNFSA-N

反应信息

• 作为反应物：
  描述：

  (η(4)-1,5-cyclooctadiene)(thioacetylacetonato)iridium 、 碘甲烷 以 丙酮 为溶剂， 生成 (η⁴-1,5-cyclooctadiene)(iodo)(methyl)(thioacetylacetonato)iridium(III)
  参考文献：
  名称：

  (η4-1,5-Cyclooctadiene)(iodo)(methyl)(thioacetylacetonato)iridium(III)

  摘要：

  The structure determination of the title complex, [Ir(C5H7OS)(CH3)(I)(C8H12)], revealed that the oxidative addition of iodomethane to (eta(4) -1,5-cyclooctadiene)(thioacetylacetonato)iridium(I) results in the formation of the trans isomer. The deviation of the I-Ir-CH3 angle [156.1(3)degrees] from linearity is attributed to steric repulsion between the CH3 group or I atom and the olefinic H atoms.

  DOI：

  10.1107/s010827019500254x