| 166897-88-7

• CAS: 166897-88-7
• 化学式: C₃H₉In*C₄H₁₀O₂
• 分子量: 250.047
• InChiKey: GQNASJUMLOJSPE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  甲基锂 、 氯化铟 以 乙二醇二甲醚 、 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Adducts of InCl3 with Lewis bases: Crystal and molecular structure of [(InCl3)2(DME)3]

  摘要：

  A number of adducts of InCl3 with selected Lewis bases have been synthesized and characterized. The complex of InCl3 with 1,2-dimethoxyethane (DME = CH3OCH2CH2OCH3) is characterized by two centrosymmetrically related InCl3 . DME . 0.5 DME units, where the indium is six-coordinated to three chlorine atoms, two oxygen atoms of one chelating DME unit and one oxygen atom of the bridging DME ligand in a fac-octahedral arrangement. The suitability and limits of using InCl3 . 3/2DME for the synthesis of InMe(3) (Me = CH3) are discussed.

  DOI：

  10.1016/0277-5387(94)00449-o