methyl 1,2-methylcymantrenylcarboxylate | 134120-94-8

• 英文名称: methyl 1,2-methylcymantrenylcarboxylate
• CAS: 134120-94-8
• 化学式: C₁₁H₉MnO₅
• 分子量: 276.127
• InChiKey: CKKUJESRFHOQAX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  methyl 1,2-methylcymantrenylcarboxylate 、 二苯二硫醚 在 四氢呋喃 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  First optically active organometallic free radical in the cymantrene series

  摘要：

  Replacement of one CO ligand in the enantiomeric 2-methylcymantrenecarboxylic acid ester for a radical ligand PhS results in the preparation of stable and optically active odd-electron complex CH3C5H3COOCH3Mn(CO)(2)SPh] fully characterized by electron spin resonance, mass spectroscopy, UV-visible spectroscopy, IR spectroscopy and circular dichroism spectroscopy. This is the first example of an optically active organometallic free radical.

  DOI：

  10.1016/0022-328x(94)05285-j