chloro(biphenyl-2,2'-diyl)tricarbonyliridium(III) | 161660-65-7

• 英文名称: chloro(biphenyl-2,2'-diyl)tricarbonyliridium(III)
• CAS: 161660-65-7
• 化学式: C₁₅H₈ClIrO₃
• 分子量: 463.9
• InChiKey: OOXKTUKWLNNYFV-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  sodium tetrahydroborate 、 chloro(biphenyl-2,2'-diyl)tricarbonyliridium(III) 以 乙醇 、 二氯甲烷 为溶剂， 以68%的产率得到Ir(PMe3)3(biphenyl-2,2'-diyl)H
  参考文献：
  名称：

  Geometrically Distorted and Redox-Active Organometallic Iridium Complexes Containing Biphenyl-2,2'-diyl

  摘要：

  C-C bond cleavage of biphenylene by an Ir(I) complex via an oxidation addition generates the biph (=biphenyl-2,2'-diyl) ligand. The resulting compound is treated with PPh(3) to give [Ir(PPh(3))(2)(biph)Cl], having a 16 e five-coordinate structure lying between Y and T geometries, being closer to a Y, which is rationalized on theoretical grounds. The complex [Ir(PMe(3))(3)-(biph)Cl] can be oxidized quasi-reversibly to an Ir(TV) species. Oxidation with NOBF4 gives the unusual Ir(IV) boryl compound [Ir(PMe(3))(3)(biphBF)Cl](+), which has been isolated and structurally characterized. Extended Huckel (EHT) calculations suggest that the easy oxidation of the {Ir(biph)} system is associated with the presence of a high-lying Ir d(yz) orbital. The {Ir(biph)} fragment is remarkably stable; only Br-2 is able to cleave the Ir-C bonds.

  DOI：

  10.1021/om00003a018
• 作为产物：
  描述：

  chloro(biphenyl-2,2'-diyl)(1,5-cyclooctadiene)iridium(III) 、 一氧化碳 以 二氯甲烷 为溶剂， 生成 chloro(biphenyl-2,2'-diyl)tricarbonyliridium(III)
  参考文献：
  名称：

  Geometrically Distorted and Redox-Active Organometallic Iridium Complexes Containing Biphenyl-2,2'-diyl

  摘要：

  C-C bond cleavage of biphenylene by an Ir(I) complex via an oxidation addition generates the biph (=biphenyl-2,2'-diyl) ligand. The resulting compound is treated with PPh(3) to give [Ir(PPh(3))(2)(biph)Cl], having a 16 e five-coordinate structure lying between Y and T geometries, being closer to a Y, which is rationalized on theoretical grounds. The complex [Ir(PMe(3))(3)-(biph)Cl] can be oxidized quasi-reversibly to an Ir(TV) species. Oxidation with NOBF4 gives the unusual Ir(IV) boryl compound [Ir(PMe(3))(3)(biphBF)Cl](+), which has been isolated and structurally characterized. Extended Huckel (EHT) calculations suggest that the easy oxidation of the {Ir(biph)} system is associated with the presence of a high-lying Ir d(yz) orbital. The {Ir(biph)} fragment is remarkably stable; only Br-2 is able to cleave the Ir-C bonds.

  DOI：

  10.1021/om00003a018