[Cp2Zr(η(3)-methallyl)](1+) | 124512-95-4

• 英文名称: [Cp2Zr(η(3)-methallyl)](1+)
• CAS: 124512-95-4
• 化学式: C₁₄H₁₇Zr
• 分子量: 276.513
• InChiKey: WWTCJLHPCQFYLS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  i-Bu2Zr(η5-C5H5)2 、 三苯碳四(五氟苯基)硼酸盐 生成 [Cp2Zr(η(3)-methallyl)](1+)
  参考文献：
  名称：

  Cationic Zirconocene Hydrides:  A New Type of Highly Effective Initiators for Carbocationic Polymerizations

  摘要：

  The reaction of [CPh3][B(C6F4R)(4)] with [Cp'(2)-ZrH2](2) (Cp' = C5H4SiMe3) gives the new binuclear hydride complexes [Cp'4Zr2H3][B(C6F4R)(4)] (R = F, SiPr3i), which are highly active initiators for the polymerization of isobutene and isobutene-isoprene copolymerizations at near-zero concentrations of ionizing solvents. The structure of the trinuclear hydride [Cp'(5)(eta(1):eta(5)-C5H3-SiMe3)Zr3H4](+)[B(C(6)F(4)SiPri(3))(4)](-) is reported.

  DOI：

  10.1021/om990304y