[(η(5)-HNMe2C2H4C5Me4)(η(4)-C4H6)Co]BF4 | 307312-36-3

• 英文名称: [(η(5)-HNMe2C2H4C5Me4)(η(4)-C4H6)Co]BF4
• CAS: 307312-36-3
• 化学式: BF₄*C₁₇H₂₉CoN
• 分子量: 393.222
• InChiKey: JRRFYAVCJZPMGI-UHFFFAOYSA-O

反应信息

• 作为反应物：
  描述：

  [(η(5)-HNMe2C2H4C5Me4)(η(4)-C4H6)Co]BF4 以 丙酮 为溶剂， 生成 [(η(1),η(5)-NMe2C2H4C5Me4)(η(3)-1-syn-MeC3H4)Co]BF4
  参考文献：
  名称：

  Amino-substituted cyclopentadienyl cobalt complexes

  摘要：

  Reduction of the (eta(1),eta(5)-R2NC2H4C5Me4)CoCl complexes (R=Me, R-2=cyclo-C4H8), prepared by treating CoCl2 with 2-dimethylaminoethyl- or 2-pyrrolidinylethyl-tetramethylcyclopentadienyl-lithium with active-Mg in the presence of ethylene or dienes leads to the formation of (eta(5)-R2NC2H4C5Me4)(CH2:CH2)(2)Co(I) or (eta(5)-R2NC2H4C5Me4)(diene)Co(I) complexes. These react with ethereal HBF, with protonation of the amine followed, in the case of the diene complexes, by transfer of the proton to the diene to give (eta(1),eta(5)-R2NC2H4C5Me4)(eta(3)-allyl)Co(III)-salts. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00244-8