| 222528-04-3

• CAS: 222528-04-3
• 化学式: C₁₅H₁₆O₂Ru₂
• 分子量: 432.415
• InChiKey: QIEULAWQXOUKSU-XLGGOEFNSA-N

反应信息

• 作为产物：
  描述：

  [(η-5-cyclopentadienyl)2Ru2(μ-CD2)(μ-CHCH3)(CO)2] 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Photochemical C–H bond activation of the diruthenium bridging methylene complex, Cp2Ru2(μ-CH2)2(CO)2: insertion of norbornadienes into the methylene C–H bond and unprecedented intramolecular H–D exchange between the two methylene units

  摘要：

  Two photochemical reactions of the diruthenium bis-µ-methylene complex (η5-C5H5)2Ru2(µ-CH2)2(CO)2 are described: (i) insertion reaction of norbornadiene into the methylene C–H bonds leading to (η5-C5H5)2Ru2(µ-CHR′)2(CO)2 (R′ = 5-exo-norbornenyl) and (ii) H exchange between the two methylene units, involve µ-methylidyne intermediates generated via C–H bond activation of the µ-methylene ligand.

  DOI：

  10.1039/a808411d