Cp(*)Ir(CO)B3H7 | 227780-60-1

• 英文名称: Cp(*)Ir(CO)B3H7
• CAS: 227780-60-1
• 化学式: C₁₁H₂₂B₃IrO
• 分子量: 394.948
• InChiKey: CCMYZPWLDLPFFF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 Cp(*)Ir(H)2B3H7 生成 Cp(*)Ir(CO)B3H7
  参考文献：
  名称：

  Novel Iridaboranes from the Reactions of Cp*₂Ir₂H_xCl_4-x, x = 0−2, with LiBH₄. Existence of a Concurrent Reaction Channel in the Conversion of Metal Chlorides to Metal Hydrides

  摘要：

  Reaction of either Cp*2Ir2Cl4 or Cp*2Ir2HCl3 with LiBH4 leads to formation of the new iridaborane Cp*Ir(H)(2)B3H7, 1 (a borallyl complex), in parallel with Cp*IrH4. In contrast, reaction, of Cp*2Ir2H2Cl2 with LiBH4 leads exclusively to Cp*Ir-2(2)(H)(3)B2H5, 3, which is isolobal with 1.

  DOI：

  10.1021/om990091c