(η5-C5H5)Re(CO)2(piperidine) | 60718-65-2

• 英文名称: (η5-C5H5)Re(CO)2(piperidine)
• 英文别名: [(η5-cyclopentadienyl)Re(CO)2(piperidine)
• CAS: 60718-65-2
• 化学式: C₁₂H₁₆NO₂Re
• 分子量: 392.472
• InChiKey: RPVFBLYFOFSQPF-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  哌啶 、 (η-5-C5H5)Re(CO)2(n-heptane) 以 正庚烷 为溶剂， 生成 (η5-C5H5)Re(CO)2(piperidine)
  参考文献：
  名称：

  Displacement of the heptane solvent from (η5-C5H5)Re(CO)2(heptane): A flash photolysis study using infrared detection

  摘要：

  The displacement of the heptane solvent molecule from the (eta(5)-C5H5)Re(CO)(2)(heptane) complex by it variety of ligands is studied. The substitution reaction proceeds through an I-d mechanism since changes in the electronic and steric properties of the incoming ligand do not influence the reaction rate significantly. Activation parameters suggest a lower limit of 57.3 +/- 0.9 kJ/mol for the strength of the Re-heptane interaction. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.07.056

文献信息

• Photophysical properties of CpRe(CO)2L complexes. Distinct orbital emissions from nonequilibrated excited states in room-temperature solution
  作者：Marsha M. Glezen、Alistair J. Lees

  DOI：10.1021/ja00199a019

  日期：1989.8