mer-[Re(III)(2-(p-chlorophenylazo)-1-methylimidazole)(OPPh2CH2PPh2)Cl3] | 311338-18-8

• 英文名称: mer-[Re(III)(2-(p-chlorophenylazo)-1-methylimidazole)(OPPh2CH2PPh2)Cl3]
• CAS: 311338-18-8
• 化学式: C₃₅H₃₁Cl₄N₄OP₂Re
• 分子量: 913.624
• InChiKey: QNOWUHUKCCAHRM-SMHVRUCUSA-K

反应信息

• 作为反应物：
  描述：

  mer-[Re(III)(2-(p-chlorophenylazo)-1-methylimidazole)(OPPh2CH2PPh2)Cl3] 以 苯 为溶剂， 生成 fac-[Re(III)(2-(p-chlorophenylazo)-1-methylimidazole)(Ph2PCH2P(O)Ph2)Cl3]*1.5benzene
  参考文献：
  名称：

  Oxygen atom transfer from RevO to tertiary diphosphines: spacer length and chemical differentiation of products

  摘要：

  The reaction of mer-[ReL(O)Cl3], [L = 2-(p-chlorophenylazo)-1-methylimidazole] with Ph2P(CH2)nPPh2 (abbreviated PnP) affords [ReL(OP1P)Cl3] 2a, [ReL(OP1PO)Cl3] 4 and [ReL(OP2P)Cl3] 2b, [Cl3LRe(OP2PO)ReLCl3] 5, all having mer geometry; unlike 2b which is stable in solution, 2a spontaneously isomerizes to fac-[ReL(P1PO)Cl3] via an associative pathway; the origin of the observed differentiation (2a vs. 2b and 4 vs. 5) is scrutinized in terms of structures and reaction models.

  DOI：

  10.1039/b004565i
• 作为产物：
  描述：

  mer-[Re(2-(p-chlorophenylazo)-1-methylimidazole)(O)Cl3] 、 双二苯基膦甲烷 以 二氯甲烷 为溶剂， 生成 mer-[Re(III)(2-(p-chlorophenylazo)-1-methylimidazole)(OPPh2CH2PPh2)Cl3]
  参考文献：
  名称：

  Oxygen atom transfer from RevO to tertiary diphosphines: spacer length and chemical differentiation of products

  摘要：

  The reaction of mer-[ReL(O)Cl3], [L = 2-(p-chlorophenylazo)-1-methylimidazole] with Ph2P(CH2)nPPh2 (abbreviated PnP) affords [ReL(OP1P)Cl3] 2a, [ReL(OP1PO)Cl3] 4 and [ReL(OP2P)Cl3] 2b, [Cl3LRe(OP2PO)ReLCl3] 5, all having mer geometry; unlike 2b which is stable in solution, 2a spontaneously isomerizes to fac-[ReL(P1PO)Cl3] via an associative pathway; the origin of the observed differentiation (2a vs. 2b and 4 vs. 5) is scrutinized in terms of structures and reaction models.

  DOI：

  10.1039/b004565i