[5-mono(pentafluorophenyl)10,15,20-tris(2,6-dichlorophenyl)2,3,7,8,12,13,17,18-octachloroporphyrin]iron(III) chloride | 851536-60-2

• 英文名称: [5-mono(pentafluorophenyl)10,15,20-tris(2,6-dichlorophenyl)2,3,7,8,12,13,17,18-octachloroporphyrin]iron(III) chloride
• 英文别名: Fe(PCl8)Cl
• CAS: 851536-60-2
• 化学式: C₄₄H₉Cl₁₅F₅FeN₄
• 分子量: 1276.22
• InChiKey: VXOGFLKMFHYPCK-CUWSATNVSA-M

反应信息

• 作为产物：
  描述：

  iron(II) chloride tetrahydrate 、 2,3,7,8,12,13,17,18-octachloro-5(pentafluorophenyl)-10,15,20-tri(2,6-dichlorophenyl)porphyrin 以 乙腈 为溶剂， 生成 [5-mono(pentafluorophenyl)10,15,20-tris(2,6-dichlorophenyl)2,3,7,8,12,13,17,18-octachloroporphyrin]iron(III) chloride
  参考文献：
  名称：

  Polymeric membranes: the role this support plays in the reactivity of the different generations of metalloporphyrins

  摘要：

  In this work, we investigated the catalytic activity of representatives of the three generations of ironporphyrins, namely [5,10,15,20-tetraphenylporphyrin]iron(III) chloride (Fe(TPP)Cl), [5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin]iron(III) chloride (Fe(TDCPP)Cl), and [5-mono(pentafluorophenyl) 10, 15,20-tris(2,6-dichlorophenyl)2,3,7,8,12,13,17,18-octachloroporphyrin] iron(Ill) (Fe(PCl8)Cl), occluded in a polymeric film based on poly(dimethylsiloxane) (PDMS), in the oxidation of cyclohexane by iodosylbenzene. The catalytic results show the influence of the polymeric support on the reactivity of the three generations of metalloporphyrins, its importance in concentrating the substrate close to the catalytic site, and the protection it renders the catalyst against auto-oxidative destruction. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.11.014