| 242131-05-1

• CAS: 242131-05-1
• 化学式: C₂₉H₃₀Fe₂N₂
• 分子量: 518.265
• InChiKey: HYWLKPOIMOSHHQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  乙酸酐 、 以 neat (no solvent) 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  The structure of bicyclic ferrocenylmethylene substituted 2-pyrazolines and their reactions with azodicarboxylic acid N-phenylimide

  摘要：

  Asymmetrical induction in the synthesis of bicyclic pyrazolines with a ferrocenyl substituent has been studied. A relatively high diastereomeric selectivity in the 'chiral-center-by-a-chiral-center' induction of the 1,2-type has been observed. Molecular geometry of a cis-diastereomer of 1-acetyl-9-ferrocenyl-4-ferrocenylmethylene-1,2-diazabicyclo[4.3.0]non-2-ene has been established. Bicyclic 2-pyrazolines having conjugated ferrocenylmethylene fragments interact with azodicarboxylic acid N-phenylimide to form diene and monoene adducts. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00202-8