| 287978-61-4

• CAS: 287978-61-4
• 化学式: C₁₂H₁₇MoO₂
• 分子量: 289.206
• InChiKey: HOJIFGMXVMLVQU-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (η5-MeC5H4)2MoCl2 在 NaOH 作用下， 以 重水 为溶剂， 生成 、
  参考文献：
  名称：

  Investigation of the Monomer−Dimer Equilibria of Molybdocenes in Water

  摘要：

  Molybdocenes form monomeric and dimeric complexes upon dissolution in water. The solution structures of the molybdocenes at neutral pH are inferred as the monomeric [(CpR)(2)Mo(OH2)(OH)](+) and the dimeric [(CpR)(2)Mo(mu-OH)(2)Mo(CpR)(2)](2+). The equilibrium constants for the monomer-dimer equilibria were obtained from H-1 NMR dilution studies as K'(eq) = (7.9 x 10(-2)) +/- (1.0 x 10(-3)) M for R = CH3 at pD 7 and as K-eq = (3.5 x 10-2) +/- (1.3 x 10(-3)) M for R = CH3 at pD 3.5. Qualitatively, the monomer of the CpMe molybdocene is more favored than the Cp analogue, compared to their respective dimers.

  DOI：

  10.1021/om000180l