| 350990-46-4

• CAS: 350990-46-4
• 化学式: BF₄*C₂₆H₂₅OPRh
• 分子量: 574.168
• InChiKey: AESVBIWOYOATKH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 、 以 二氯甲烷 为溶剂， 生成 、
  参考文献：
  名称：

  Stereospecific CO Insertion into the Rhodium−Methyl σ Bond in [(Cp‘-P)Rh(CO)(Me)]BF₄ and Deinsertion from [(Cp‘-P)Rh(COMe)I]:  Experimental Evidence for Methyl Migration

  摘要：

  We have shown concrete evidence for migration of an alkyl group in. carbonyl insertion, and deinsertion steps between the methyl carbonyl rhodium complex [{eta (5):eta (1)-(Ind-P)(n=3)}Rh(CO)Me]BF4 (3) and the acetyl rhodium complex {eta (5):eta (1)-(Ind-P)(n=3)}RhI(COMe) (1) by crystallography as well as by H-1 NMR spectroscopy.

  DOI：

  10.1021/om010143+
• 作为产物：
  描述：

  silver tetrafluoroborate 、 、 以 二氯甲烷 为溶剂， 生成 、
  参考文献：
  名称：

  Stereospecific CO Insertion into the Rhodium−Methyl σ Bond in [(Cp‘-P)Rh(CO)(Me)]BF₄ and Deinsertion from [(Cp‘-P)Rh(COMe)I]:  Experimental Evidence for Methyl Migration

  摘要：

  We have shown concrete evidence for migration of an alkyl group in. carbonyl insertion, and deinsertion steps between the methyl carbonyl rhodium complex [{eta (5):eta (1)-(Ind-P)(n=3)}Rh(CO)Me]BF4 (3) and the acetyl rhodium complex {eta (5):eta (1)-(Ind-P)(n=3)}RhI(COMe) (1) by crystallography as well as by H-1 NMR spectroscopy.

  DOI：

  10.1021/om010143+