PtCl2(1-diphenylphosphino-2,1'-[1-diphenylphosphino-1,3-propanediyl]ferrocene) | 260412-13-3

• 英文名称: PtCl2(1-diphenylphosphino-2,1'-[1-diphenylphosphino-1,3-propanediyl]ferrocene)
• CAS: 260412-13-3
• 化学式: C₃₇H₃₂Cl₂FeP₂Pt
• 分子量: 860.442
• InChiKey: HGEMNNDHIAWHCP-PGZFOHQRSA-L

反应信息

• 作为反应物：
  描述：

  potassium cyanide 、 PtCl2(1-diphenylphosphino-2,1'-[1-diphenylphosphino-1,3-propanediyl]ferrocene) 以 甲醇 为溶剂， 以84%的产率得到Pt(CN)2(1-diphenylphosphino-2,1'-[1-diphenylphosphino-1,3-propanediyl]ferrocene)
  参考文献：
  名称：

  Synthesis and NMR investigation of Pt(CN)2(diphosphine) and [Pt(CN)(triphosphine)]Cl complexes

  摘要：

  Pt(CN)(2)(Ph2P(CH2)(n)PPh2) (n = 2,3,4) and Pt(CN)(2)(P-1-P-2) (P-1-P-2 = 1-diphenylphosphino-2,1'-[(1-diphenylphosphino)-1,3-propanediyl]-ferrocene, 1-diphenylphosphino-2,1'-[(1-dicyclohexylphosphino)-1.3-propanediyl]-ferrocene) were synthesised by reacting potassium cyanide and the corresponding PtCl2(diphosphine) complexes. PtCl(CN)(diphosphine) complexes were identified as minor products when KCN/PtCl2(diphosphine) molar ratio was kept below 2. The use of KCN in excess resulted in the formation of K2Pt(CN)(4). [Pt(CN)({Ph2P(CH2)(2)}(2)PPh)](+) complex cation and Pt(CN)(2))({Ph2P(CH2)(2)}(2)PPh) five-coordinate covalent complex of fluxional behaviour were obtained at KCN/Pt ratio of 1 and 2, respectively. The platinum-cyano complexes were characterised by NMR spectroscopy. The direct Pt-CN bond was proved by (1)J(Pt-195,P-31), (2)J(P-31,C-13) coupling constants by using sodium cyanide-C-13 for ligand exchange reactions. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00042-6

文献信息

• Platinum complexes of heteroannularly bridged heterobidentate ferrocenyl diphosphine ligands: their molecular structure and their use in catalytic carbonylation reactions
  作者：Thomas Sturm、Walter Weissensteiner、Kurt Mereiter、Tamás Kégl、György Jeges、György Petőlz、László Kollár

  DOI：10.1016/s0022-328x(99)00584-7

  日期：2000.1

  Platinum complexes PtCl2(L) and PtCl(SnCl3)(L) of the ferrocenyl diphosphine ligands (L) (R,R)-1-diphenylphosphino-2,1'-[(1-diphenylphosphino)-1,3-propanediyl]-ferrocene (1), (R,R)-1-diphenylphosphino-2,1'-[(1-dicyclohexylphosphino)-1,3-propanediyl]ferrocene (2), (R,R)-1-bis(4-fluorophenyl)phosphino-2,1'-[(1-diphenylphosphino)-1,3-propanediyl]-ferrocene (3), have been synthesised. Complexes PtCl2(1) and PtCl2(2) have been structurally characterised by X-ray diffraction. Both the 'preformed' and the in situ catalysts have been used in hydroformylations of styrene. At low temperature (below 70 degrees C) and with use of the platinum catalysts the prevailing formation of (R)-2-phenyl-propanal was observed, while at higher temperatures the formation of the (S)-enantiomer was favoured. The palladium catalysts proved to be rather inactive in the hydromethoxycarbonylation of styrene. In the presence of ligand 2 the predominant formation of the linear regioisomer was observed. (C) 2000 Elsevier Science S.A. All rights reserved.