Crystal Structure and Electrochemical Properties of Ferrocenyl Aminophosphonic Esters
摘要:
A series of novel compounds of aminophosphonates bearing the ferrocenyl moiety are obtained. X-ray Crystallography of 2c reveals that it belongs to monoclinic system with space group P2(1)/c, R1 = 0.0620, wR2 = 0.1516. The cyclic voltammetric behavior of these compounds show one pair of quasi-reversible and redox waves in the potential range of 0.0-1.0 V and it is controlled by diffusion. The diffusion coefficient decrease with increasing in the molecular weight of the compounds and the size of the molecules. CCDC: 679937
Synthesis, structures and electrochemistry of two Schiff base compounds bearing phenylferrocene
摘要:
Two novel ferrocene derivatives, FcL(1) and FcL(2), were prepared and characterized. The X-ray crystal structure of FcL(1) was also described. The electrochemical studies reveal that oxidation of the substituents on the ferrocene moiety leads to an electrode passivation process. (C) 2004 Published by Elsevier B.V.