2-(2'-thiazole)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide | 844644-99-1

• 英文名称: 2-(2'-thiazole)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide
• CAS: 844644-99-1
• 化学式: C₁₀H₁₆N₃O₂S
• 分子量: 242.322
• InChiKey: VHTPXTUTMVHPMM-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  nickel(II) perchlorate hexahydrate 、 2-(2'-thiazole)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide 以 乙醇 为溶剂， 生成 Ni(2-(2'-thiazole)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)3(ClO4)2
  参考文献：
  名称：

  Synthesis, crystal structure and magnetic properties of a novel complex Ni(NIT2-thz)3(ClO4)2

  摘要：

  A novel Ni(II)-nitronyl nitroxide-substituted thiazole complex, Ni(NIT2-thz)(3)(ClO4)(2) (NIT2-thz = 2-(2'-thiazole)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized structurally and magnetically. It crystallizes in the monoclinic space group P2(1)c. The metal coordination sphere is fully occupied by three chelating nitroxide ligands, showing a distorted octahedral geometry. The complex molecules were connected as 1-D chain structure by the intermolecular interaction. Magnetic studies show that antiferromagnetic couplings occurred between the nickel(H) ion and the organic radicals, and ferromagnetic between the adjacent molecules. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.09.050

文献信息

• Wang, Li-Ya; Zhang, Chen-Xi; Liu, Zhan-Quan, Inorganic Chemistry Communications, <hi>2003</hi>, vol. 6, p. 1255 - 1258
  作者：Wang, Li-Ya、Zhang, Chen-Xi、Liu, Zhan-Quan、Liao, Dai-Zheng、Jiang, Zong-Hui、Yan, Shi-Ping

  DOI：——

  日期：——