(1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-4-yl)phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η²:η²-cycloocta-1,5-iene)iodidoiridium(I) iodide | 1392231-65-0

• 英文名称: (1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-4-yl)phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η²:η²-cycloocta-1,5-iene)iodidoiridium(I) iodide
• 英文别名: [IrI(COD)(κ¹-^DippTrzTrz(H))][I]
• CAS: 1392231-65-0
• 化学式: C₄₄H₅₇IIrN₆*I
• 分子量: 1116.01
• InChiKey: GMWQUBBXNPPFLE-KJWGIZLLSA-L

反应信息

• 作为反应物：
  描述：

  methoxy(cyclooctadiene)rhodium(I) dimer 、 (1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-4-yl)phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η²:η²-cycloocta-1,5-iene)iodidoiridium(I) iodide 在 potassium iodide 作用下， 以 乙腈 为溶剂， 反应 1.0h， 以80%的产率得到(1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)((η²:η²-cycloocta-1,5-diene)iodidoiridium(I))phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I)
  参考文献：
  名称：

  Di-Mesoionic Carbene-Bridged Complexes of Rh₂, Ir₂, and RhIr: A Stepwise Metalation Strategy for the Synthesis of di-MIC-Bridged Mixed-Metal Systems

  摘要：

  A meta-substituted benzene-bridged ditriazolium salt has been prepared using copper-catalyzed azide-alkyne cycloaddition (CuAAC or "click" chemistry) and methylation protocols. Metalation of this dicationic species by basic-ligand-containing [Rh(mu-OMe)(COD)](2) and [Ir(mu-OMe)(COD)](2) precursors provides homobimetallic complexes of Rh and Jr bridged by a 1,2,3-triazol-5-ylidene-type di-mesoionic carbene (di-MIC) via an "internal-base" strategy. By using only 1/2 equiv of the internal-base precursor, mononuclear MIC-anchored/pendent-triazolium intermediates have been isolated, in which only one end of the ditriazolium salt has been deprotonated and attached to Rh or Jr. Reaction of these pendent intermediates with another 1/2 equiv of an internal-base precursor affords either the aforementioned homobimetallic products or an analogous di-MIC-bridged, mixed-metal Ir/Rh complex.

  DOI：

  10.1021/om300423z
• 作为产物：
  描述：

  (1,5-cyclooctadiene)(methoxy)iridium(I) dimer 、 4,4′-(1,3-phenylene)bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium) trifluoromethanesulfonate 在 potassium iodide 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以81%的产率得到(1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-4-yl)phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η²:η²-cycloocta-1,5-iene)iodidoiridium(I) iodide
  参考文献：
  名称：

  Di-Mesoionic Carbene-Bridged Complexes of Rh₂, Ir₂, and RhIr: A Stepwise Metalation Strategy for the Synthesis of di-MIC-Bridged Mixed-Metal Systems

  摘要：

  A meta-substituted benzene-bridged ditriazolium salt has been prepared using copper-catalyzed azide-alkyne cycloaddition (CuAAC or "click" chemistry) and methylation protocols. Metalation of this dicationic species by basic-ligand-containing [Rh(mu-OMe)(COD)](2) and [Ir(mu-OMe)(COD)](2) precursors provides homobimetallic complexes of Rh and Jr bridged by a 1,2,3-triazol-5-ylidene-type di-mesoionic carbene (di-MIC) via an "internal-base" strategy. By using only 1/2 equiv of the internal-base precursor, mononuclear MIC-anchored/pendent-triazolium intermediates have been isolated, in which only one end of the ditriazolium salt has been deprotonated and attached to Rh or Jr. Reaction of these pendent intermediates with another 1/2 equiv of an internal-base precursor affords either the aforementioned homobimetallic products or an analogous di-MIC-bridged, mixed-metal Ir/Rh complex.

  DOI：

  10.1021/om300423z