| 444599-65-9

• CAS: 444599-65-9
• 化学式: C₃₄H₇₀Br₃Mg₂N₈Sc
• 分子量: 924.261
• InChiKey: RUWLXUCDKZNVQF-ISYGIHGASA-K

反应信息

• 作为反应物：
  描述：

  tris(pentafluorophenyl)borane hydrate 、 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Elucidation of a Sc(I) Complex by DFT Calculations and Reactivity Studies

  摘要：

  Sc(BrMgL)(2)Br (L = (R2NCH2CH2NCMe)(2)CH, R = H) was studied by DFT methods leading to the conclusion that this diamagnetic formal scandium(I) system enjoys stabilization of its Sc-based filled d(yz) orbital by a delta-acceptor linear combination of BrMgL ring orbitals. Investigation of the reactivity of Sc(BrMgL)2Br (L = (R2NCH2CH2NCMe)2CH, R = Et) with H2O.B(C6F5)(3) and (HOCH2)(2)CMe2, respectively, led to decomposition, with LMgBr being isolated in the latter case.

  DOI：

  10.1021/ic034947o
• 作为产物：
  描述：

  、 烯丙基溴化镁 以 乙醚 为溶剂， 以25%的产率得到
  参考文献：
  名称：

  Elucidation of a Sc(I) Complex by DFT Calculations and Reactivity Studies

  摘要：

  Sc(BrMgL)(2)Br (L = (R2NCH2CH2NCMe)(2)CH, R = H) was studied by DFT methods leading to the conclusion that this diamagnetic formal scandium(I) system enjoys stabilization of its Sc-based filled d(yz) orbital by a delta-acceptor linear combination of BrMgL ring orbitals. Investigation of the reactivity of Sc(BrMgL)2Br (L = (R2NCH2CH2NCMe)2CH, R = Et) with H2O.B(C6F5)(3) and (HOCH2)(2)CMe2, respectively, led to decomposition, with LMgBr being isolated in the latter case.

  DOI：

  10.1021/ic034947o