TaN(2,6-Me2C6H3)Cl3(THF)2 | 643739-26-8

• 英文名称: TaN(2,6-Me2C6H3)Cl3(THF)2
• CAS: 643739-26-8
• 化学式: C₁₆H₂₅Cl₃NO₂Ta
• 分子量: 550.687
• InChiKey: YDIAANGYCARSND-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  TaN(2,6-Me2C6H3)Cl3(THF)2 、 以 四氢呋喃 、 乙醇 为溶剂， 以41.5%的产率得到(iPr)HN[N(iPr)]CN(CH2)2NC[NH(iPr)]N(iPr)
  参考文献：
  名称：

  Catalytic CN bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands

  摘要：

  A family of guanidinate-supported imido metal complexes are novel, effective catalysts for CN metathesis of alkyl and aryl carbodiimides and evidence suggests that this reaction proceeds via a sequential addition/elimination pathway.

  DOI：

  10.1039/b308710g