| 402559-57-3

• CAS: 402559-57-3
• 化学式: C₂₁H₁₅FeO₂Rh
• 分子量: 458.101
• InChiKey: PHCPTJFYHVNHJX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 p-benzoquinone 、 NH₄PF₆ 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Heterobimetallic (Ferrocenyl)indenyl Rhodium Complexes. Synthesis, Crystal Structure, and Oxidative Activation of [η⁵-(1-Ferrocenyl)indenyl]RhL₂ [L₂ = COD, NBD, (CO)₂]

  摘要：

  The binuclear [eta(5)-(1-ferrocenyl)indenyl]Rh(NBD) (1), [eta(5)-(1-ferrocenyl)indenyl]Rh(COD) (1a), and [eta(5)-(1-ferrocenyl)indenyl]Rh(CO)2 (2) complexes have been synthesized (NBD = norbornadiene; COD = cyclooeta-1,5-diene). The crystal structure determination showed that the iron and rhodium nuclei are disposed in a transoid configuration in 1 probably to avoid steric repulsions. On the contrary, in 2 the metals are in a cisoid configuration due to the presence of stabilizing pi-hydrogen bonds between the CO's and the hydrogens of the unsubstituted cyclopentadienyl ring. The results of the chemical and electrochemical oxidation of 2 are in favor of the existence of an effective interaction between the two metals.

  DOI：

  10.1021/om010621g