(R,R)-LaLi3(binaphthoxide)2((CH3OC6H3O)2) | 912366-53-1

• 英文名称: (R,R)-LaLi3(binaphthoxide)2((CH3OC6H3O)2)
• CAS: 912366-53-1
• 化学式: C₅₄H₃₆LaLi₃O₈
• 分子量: 972.604
• InChiKey: IYYBKZQZYREKTK-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  trilithium tris[(R)-1,1'-bi(2-naphtholato)]lanthanate 、 (R)-LaLi3tris((MeOC6H3O)2) 生成 (R,R)-LaLi3(binaphthoxide)((CH3OC6H3O)2)2 、 (R,R)-LaLi3(binaphthoxide)2((CH3OC6H3O)2)
  参考文献：
  名称：

  Mixed La−Li Heterobimetallic Complexes for Tertiary Nitroaldol Resolution

  摘要：

  A kinetic resolution of tertiary nitroaldols derived from simple ketones is described. Mixed BINOL/biphenol La-Li heterobimetallic complexes gave the best selectivity in retro-nitroaldol reactions of racemic tertiary nitroaldols. By using a mixture of La-Li3-(1a)3 complex (LLB 2a) and La-Li3-(1b)3 (LLB* 2b) complex in a ratio of 2/1, chiral tertiary nitroaldols were obtained in 80-97% ee and 30-47% recovery yield.

  DOI：

  10.1021/ja064858l