[Mo(η5-SC6H3-2,6-(SiMe3)2)(η7-SC6H3-2,6-(SiMe3)2)] | 503454-31-7

• 英文名称: [Mo(η5-SC6H3-2,6-(SiMe3)2)(η7-SC6H3-2,6-(SiMe3)2)]
• CAS: 503454-31-7
• 化学式: C₂₄H₄₂MoS₂Si₄
• 分子量: 603.011
• InChiKey: UDJVWWQASYOAEK-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  [Mo(η5-SC6H3-2,6-(SiMe3)2)(η7-SC6H3-2,6-(SiMe3)2)] 、 乙腈 以 乙腈 为溶剂， 以76%的产率得到[Mo(SC6H3-2,6-(SiMe3)2)2(η1-CH3CN)2(η2-CH3CN)]
  参考文献：
  名称：

  Unusual Coordination Modes of Arylthiolates in Mo{η⁵-SC₆H₃-2,6-(SiMe₃)₂}{η⁷-SC₆H₃-2,6-(SiMe₃)₂}

  摘要：

  Treatment of MoCl(3)(thf)(3) with LiSC(6)H(3)-2,6-(SiMe(3))(2) (LiSAr) resulted in formation of the pi-sandwiched bis-arylthiolato complex, Mo(eta(5)-SC(6)H(3)-2,6-(SiMe(3))(2))(eta(7)-SC(6)H(3)-2,6-(SiMe(3))(2)) (1), while the analogous reaction with LiSC(6)H(3)-2-Ph-6-SiMe(3) afforded the trithiolate complex Mo(SC(6)H(3)-2-Ph-6-SiMe(3))(3) (3). The acetonitrile adduct Mo(SAr)(2)(CH(3)CN)(3) (2) was isolated from the CH(3)CN solution of 1, in which one acetonitrile is coordinated to the metal center in an eta(2)-fashion. Structures of 1, 2, and 3 have been determined by X-ray diffraction.

  DOI：

  10.1021/ja029541+
• 作为产物：
  描述：

  trichlorotris(tetrahydrofuran)molybdenum(III) 、 lithium 2,6-bis(trimethylsilyl)phenylthiolate 以 乙醚 为溶剂， 以29%的产率得到[Mo(η5-SC6H3-2,6-(SiMe3)2)(η7-SC6H3-2,6-(SiMe3)2)]
  参考文献：
  名称：

  Unusual Coordination Modes of Arylthiolates in Mo{η⁵-SC₆H₃-2,6-(SiMe₃)₂}{η⁷-SC₆H₃-2,6-(SiMe₃)₂}

  摘要：

  Treatment of MoCl(3)(thf)(3) with LiSC(6)H(3)-2,6-(SiMe(3))(2) (LiSAr) resulted in formation of the pi-sandwiched bis-arylthiolato complex, Mo(eta(5)-SC(6)H(3)-2,6-(SiMe(3))(2))(eta(7)-SC(6)H(3)-2,6-(SiMe(3))(2)) (1), while the analogous reaction with LiSC(6)H(3)-2-Ph-6-SiMe(3) afforded the trithiolate complex Mo(SC(6)H(3)-2-Ph-6-SiMe(3))(3) (3). The acetonitrile adduct Mo(SAr)(2)(CH(3)CN)(3) (2) was isolated from the CH(3)CN solution of 1, in which one acetonitrile is coordinated to the metal center in an eta(2)-fashion. Structures of 1, 2, and 3 have been determined by X-ray diffraction.

  DOI：

  10.1021/ja029541+