| 700842-98-4

• CAS: 700842-98-4
• 化学式: C₂₃H₂₄NOPZr
• 分子量: 452.647
• InChiKey: UKCXUMKACFBRMU-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  以 氘代四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes

  摘要：

  Electron-deficient imines are shown to insert into the zirconium-carbon bond of azazirconacyclobutenes to generate new six-membered ring metallacycles. On heating, these expanded zirconacycles undergo a retro[4 + 2] cycloaddition to generate alpha,beta-unsaturated imines in excellent yields and novel, fully characterized electron-deficient imidozirconocene complexes.

  DOI：

  10.1021/om0497994