4-(4-ferrocenylphenyl)-1H-tetrazole | 917242-53-6

• 英文名称: 4-(4-ferrocenylphenyl)-1H-tetrazole
• CAS: 917242-53-6
• 化学式: C₁₇H₁₄FeN₄
• 分子量: 330.172
• InChiKey: ZNJBNNYLCUNRPH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  iron(II) perchlorate hexahydrate 、 4-(4-ferrocenylphenyl)-1H-tetrazole 以 甲醇 、 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Solid-state structure of a tetrazole-substituted ferrocenium salt with weak intermolecular C–H⋯N hydrogen bonds

  摘要：

  A perchlorate salt of ferrocenylphenyltetrazole has been prepared and characterized crystallographically. In the crystal, tape-like one-dimensional molecular arrangements are formed by weak CH. . .N intermolecular hydrogen bonds between the tetrazole moieties (H. . .N distance: 2.49 angstrom). A layer-like structure was formed, composed of neutral layers of phenyltetrazole moieties and ionic layers of ferrocenium moieties and anions. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.11.032
• 作为产物：
  描述：

  sodium azide 、 4-ferrocenylaniline 在 trimethyl orthoformate 作用下， 以 溶剂黄146 为溶剂， 以68%的产率得到4-(4-ferrocenylphenyl)-1H-tetrazole
  参考文献：
  名称：

  Synthesis and properties of azole-substituted ferrocenes

  摘要：

  4-Ferrocenyltriazole, 4-(4-ferrocenylphenyl)triazole, 4-ferrocenyltetrazole, and 4-(4-ferrocenylphenyl)tetrazole have been prepared. Redox potentials and decomposition temperatures were evaluated and all the compounds were crystallographically characterized; in most cases, weak intermolecular (CHN)-N-... hydrogen bonds ((HN)-N-... dist. = 2.3-2.5 angstrom) were formed between the azole moieties. Two polymorphs were found for 4-ferrocenyltetrazole, formed with either (CHN)-N-... or pi-pi interactions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.020