trans-[(C5H5)RuH2(1-diphenylphosphino-2,1'-(1-diphenylphosphinopropanediyl)-ferrocene)](O2CCF3) | 725232-53-1

• 英文名称: trans-[(C5H5)RuH2(1-diphenylphosphino-2,1'-(1-diphenylphosphinopropanediyl)-ferrocene)](O2CCF3)
• CAS: 725232-53-1
• 化学式: C₂F₃O₂*C₄₂H₃₉FeP₂Ru
• 分子量: 875.652
• InChiKey: JSVWFZWRVCSSQM-WYIGRIARSA-M

反应信息

• 作为反应物：
  描述：

  trans-[(C5H5)RuH2(1-diphenylphosphino-2,1'-(1-diphenylphosphinopropanediyl)-ferrocene)](O2CCF3) 以 乙醚 、 丙酮 为溶剂， 生成 [(C5H5)Ru(O2CCF3)(1-diphenylphosphino-2,1'-(1-diphenylphosphinopropanediyl)-ferrocene)]
  参考文献：
  名称：

  Monocyclopentadienylhydride Derivatives of Ruthenium:  Stereoselective Proton Transfer and Proton-Hydride Exchange in an Extremely Short Dihydrogen Bond

  摘要：

  Diastereomerically pure complexes of formula CpRuCl(PP*) and CpRuH(PP*) with chiral ferrocenyl diphosphines were prepared and the selectivity of proton-transfer processes over the monohydride compounds with different acids was studied. With 1 equiv of HBF4 the cis-dihydrogen and trans-dihydride complexes were formed while with 3 equiv of CF3CO2H the trans-dihydride derivative was the only product. However, the use of 1 equiv of CF3CO2H led to a dihydrogen bonded complex with an extremely short RuH...HO2CF3 interaction that exhibits proton-hydride exchange. Using the labeled acid CF3CO2D, a stereoselective transference of the deuteron was demonstrated that implies the previous epimerization of the monohydride and the subsequent attack of the acid in the position previously occupied by the hydride.

  DOI：

  10.1021/ja031926k
• 作为产物：
  描述：

  、 三氟乙酸 以 氘代丙酮 为溶剂， 生成 trans-[(C5H5)RuH2(1-diphenylphosphino-2,1'-(1-diphenylphosphinopropanediyl)-ferrocene)](O2CCF3)
  参考文献：
  名称：

  Monocyclopentadienylhydride Derivatives of Ruthenium:  Stereoselective Proton Transfer and Proton-Hydride Exchange in an Extremely Short Dihydrogen Bond

  摘要：

  Diastereomerically pure complexes of formula CpRuCl(PP*) and CpRuH(PP*) with chiral ferrocenyl diphosphines were prepared and the selectivity of proton-transfer processes over the monohydride compounds with different acids was studied. With 1 equiv of HBF4 the cis-dihydrogen and trans-dihydride complexes were formed while with 3 equiv of CF3CO2H the trans-dihydride derivative was the only product. However, the use of 1 equiv of CF3CO2H led to a dihydrogen bonded complex with an extremely short RuH...HO2CF3 interaction that exhibits proton-hydride exchange. Using the labeled acid CF3CO2D, a stereoselective transference of the deuteron was demonstrated that implies the previous epimerization of the monohydride and the subsequent attack of the acid in the position previously occupied by the hydride.

  DOI：

  10.1021/ja031926k