| 1273578-75-8

• CAS: 1273578-75-8
• 化学式: C₄₁H₄₃ClCoN₅O₄S₄
• 分子量: 892.534
• InChiKey: HAADJQSCXDLDBZ-YLOABYBBSA-K

反应信息

• 作为反应物：
  描述：

  、 氯化苄 在 NaBH₄ 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Benzyl cobaloximes with thiodioximes: Synthesis, structure and reactivity

  摘要：

  Five benzyl cobaloximes with different thiodioximes, BnCo[d(SR)gH](2)Py, have been synthesized and four of these complexes have been characterized by X-ray. The reactivity of these complexes towards molecular oxygen has been studied. The puckering of the Co(dioxime)(2) unit, caused by dioxime side chain, the SR group, significantly influences the Co-C bond reactivity. Structural features in one of the oxygen inserted cobaloximes have been studied to confirm if puckering of dioxime is the guiding factor. The reactivity is also affected, to some extent, by the C-H center dot center dot center dot pi. interaction between the benzyl and the dioxime moiety. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.10.066
• 作为产物：
  描述：

  吡啶 、 cobalt(II) chloride hexahydrate 、 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Benzyl cobaloximes with thiodioximes: Synthesis, structure and reactivity

  摘要：

  Five benzyl cobaloximes with different thiodioximes, BnCo[d(SR)gH](2)Py, have been synthesized and four of these complexes have been characterized by X-ray. The reactivity of these complexes towards molecular oxygen has been studied. The puckering of the Co(dioxime)(2) unit, caused by dioxime side chain, the SR group, significantly influences the Co-C bond reactivity. Structural features in one of the oxygen inserted cobaloximes have been studied to confirm if puckering of dioxime is the guiding factor. The reactivity is also affected, to some extent, by the C-H center dot center dot center dot pi. interaction between the benzyl and the dioxime moiety. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.10.066