| 1612790-30-3

• CAS: 1612790-30-3
• 化学式: C₂₈H₃₈Cl₂Cu₂N₄O₄
• 分子量: 692.632
• InChiKey: GQGJEEGYKPRPTM-JCUPADSXSA-J

反应信息

• 作为产物：
  描述：

  N-(2-氨基乙基)吗啉 、 2'-羟基苯乙酮 以 甲醇 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  Construction of chlorido-bridged dinuclear copper(II) complexes with similar tridentate Schiff bases

  摘要：

  Two new chlorido-bridged dinuclear copper(II) complexes [Cu2Cl2(L-1)(2)] (1) and [Cu2Cl2(L-2)(2)] (2), where L-1 and L-2 are the deprotonated form of Schiff bases 2-[1-(2-morpholin-4-ylethylimino)ethyl]phenol (HL1) and 2-[1-(2-piperidin-1-ylethylimino)ethyl]phenol respectively, are prepared and structurally characterized by elemental analysis, IR spectra, and single crystal X-ray crystallography. Complex 1 crystallizes in the monoclinic space group P2(1)/c with unit cell dimensions a = 8.0816(2) , b = 19.1780(3) , c = 9.6757(3) , beta = 106.465(2)A degrees, V = 1438.13(6) (3), Z = 2, R (1) = 0.0409, and wR (2) = 0.1085. Complex 2 crystallizes in the monoclinic space group P2(1)/c with unit cell dimensions a = 7.7640(10) , b = 19.930(3) , c = 9.628(2) , beta = 103.890(3)A degrees, V = 1446.2(4) (3), Z = 2, R (1) = 0.0634, and wR (2) = 0.1316. Each Cu atom in the complexes is coordinated by three donor atoms of the Schiff bases and by two bridging Cl atoms, forming square pyramidal geometry. The Cl anions are preferred bridging groups for the construction of dinuclear copper complexes with tridentate Schiff bases.

  DOI：

  10.1134/s0022476613060206