(μ-pdt)[Fe2(CO)5(N-diphenylphosphino-o-diaminobenzene)] | 1058743-80-8

• 英文名称: (μ-pdt)[Fe2(CO)5(N-diphenylphosphino-o-diaminobenzene)]
• 英文别名: (μ-1,3-propanedithiolato)[Fe2(CO)5(N-diphenylphosphino-o-diaminobenzene)]
• CAS: 1058743-80-8
• 化学式: C₂₆H₂₃Fe₂N₂O₅PS₂
• 分子量: 650.279
• InChiKey: GRYRDVJJQFNOLN-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  三氟甲磺酸 、 (μ-pdt)[Fe2(CO)5(N-diphenylphosphino-o-diaminobenzene)] 以 氘代乙腈 为溶剂， 生成 (μ-pdt)[Fe2(CO)5(N-diphenylphosphino-o-diaminobenzene(+1H))](1+)
  参考文献：
  名称：

  Pendant bases as proton transfer relays in diiron dithiolate complexes inspired by [Fe–Fe] hydrogenase active site

  摘要：

  Three dinuclear iron complexes containing pendant nitrogen bases in phosphine ligands with general formular ( l- pdt) [ Fe2( CO) 5L] ( where pdt is SCH2CH2CH2S, L = PPh2NH( CH2) 2N( CH3) 2 ( 5), PPh2NH( 2- NH2C6H4) ( 6), PPh2[ 2- N( CH3) 2CH2C6H4] ( 7)), were prepared as the models of the [ Fe - Fe] hydrogenase active site. The molecular structures of 5 - 7 were characterized by X- ray crystallography. The secondary amine in 6 has weak intramolecular hydrogen bonding with both the terminal nitrogen and sulfur atom, which may suggest a proton transfer pathway from amine in phosphine ligand to the sulfur atom of active site. Protonation of complexes 5 and 6 only occurred at the terminal nitrogen atom. Electrochemical properties of the complexes were studied in the presence of tri. ic acid by cyclic voltammetry. (c) 2008 Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2008.06.001
• 作为产物：
  描述：

  1,3-(μ-propanedithiolato)diironhexacarbonyl 、 N-diphenylphosphino-o-diaminobenzene 在 (CH₃)3NO*2H₂O 作用下， 以 乙腈 为溶剂， 以55%的产率得到(μ-pdt)[Fe2(CO)5(N-diphenylphosphino-o-diaminobenzene)]
  参考文献：
  名称：

  Pendant bases as proton transfer relays in diiron dithiolate complexes inspired by [Fe–Fe] hydrogenase active site

  摘要：

  Three dinuclear iron complexes containing pendant nitrogen bases in phosphine ligands with general formular ( l- pdt) [ Fe2( CO) 5L] ( where pdt is SCH2CH2CH2S, L = PPh2NH( CH2) 2N( CH3) 2 ( 5), PPh2NH( 2- NH2C6H4) ( 6), PPh2[ 2- N( CH3) 2CH2C6H4] ( 7)), were prepared as the models of the [ Fe - Fe] hydrogenase active site. The molecular structures of 5 - 7 were characterized by X- ray crystallography. The secondary amine in 6 has weak intramolecular hydrogen bonding with both the terminal nitrogen and sulfur atom, which may suggest a proton transfer pathway from amine in phosphine ligand to the sulfur atom of active site. Protonation of complexes 5 and 6 only occurred at the terminal nitrogen atom. Electrochemical properties of the complexes were studied in the presence of tri. ic acid by cyclic voltammetry. (c) 2008 Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2008.06.001