Cp*Ru(2-N-phenylamino-4-N-phenylimino-2-pentene(-H)) | 1016932-17-4

• 英文名称: Cp*Ru(2-N-phenylamino-4-N-phenylimino-2-pentene(-H))
• CAS: 1016932-17-4
• 化学式: C₂₇H₃₂N₂Ru
• 分子量: 485.634
• InChiKey: PRXLJUMCFWPYHT-CZGRFQMCSA-N

反应信息

• 作为反应物：
  描述：

  Cp*Ru(2-N-phenylamino-4-N-phenylimino-2-pentene(-H)) 、 一氧化碳 以 正己烷 为溶剂， 以99%的产率得到Cp*Ru(2-N-phenylamino-4-N-phenylimino-2-pentene(-H))CO
  参考文献：
  名称：

  Synthesis and structural characterization of a coordinatively unsaturated ruthenium complex, Cp∗Ru(Ph2nacnac), and its CO adduct

  摘要：

  Two new half sandwich ruthenium complexes with 2-N-phenylamino-4-N-phenylimino-2-pentene (Ph(2)nacnac) ligands have been synthesized and characterized. Single crystal X-ray diffraction analysis reveals the monomeric, highly air sensitive complex Cp*Ru(Ph(2)nacnac) (4) has a coordinatively unsaturated structure and the coordination environment around Ru(Ii) is effectively a triangle made up of Ct(Cp*)-N(1)-N(2). An air stable complex Cp*Ru(Ph(2)nacnac)(CO) (5) is prepared by reaction of 4 with CO, and has a pseudo-tetrahedral geometry around the Ru(II) center, made up of Ct(Cp*)-N(l)-N(2)-C(28). (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.002
• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)] 、 2-N-phenylamino-4-N-phenylimino-2-pentene 在 K₂CO₃ 作用下， 以 甲醇 为溶剂， 以81%的产率得到Cp*Ru(2-N-phenylamino-4-N-phenylimino-2-pentene(-H))
  参考文献：
  名称：

  Synthesis and structural characterization of a coordinatively unsaturated ruthenium complex, Cp∗Ru(Ph2nacnac), and its CO adduct

  摘要：

  Two new half sandwich ruthenium complexes with 2-N-phenylamino-4-N-phenylimino-2-pentene (Ph(2)nacnac) ligands have been synthesized and characterized. Single crystal X-ray diffraction analysis reveals the monomeric, highly air sensitive complex Cp*Ru(Ph(2)nacnac) (4) has a coordinatively unsaturated structure and the coordination environment around Ru(Ii) is effectively a triangle made up of Ct(Cp*)-N(1)-N(2). An air stable complex Cp*Ru(Ph(2)nacnac)(CO) (5) is prepared by reaction of 4 with CO, and has a pseudo-tetrahedral geometry around the Ru(II) center, made up of Ct(Cp*)-N(l)-N(2)-C(28). (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.11.002