1-(ferrocenylpropyl)-3-methylimidazolium chloride | 1422351-78-7

• 英文名称: 1-(ferrocenylpropyl)-3-methylimidazolium chloride
• CAS: 1422351-78-7
• 化学式: C₁₇H₂₁FeN₂*Cl
• 分子量: 344.667
• InChiKey: VBYGRGSLIJVFGM-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 1-(ferrocenylpropyl)-3-methylimidazolium chloride 以90%的产率得到
  参考文献：
  名称：

  Synthesis, characterization, and electrochemical properties of ferrocenylimidazolium

  摘要：

  A series of ferrocene-based methylimidazolium receptors were prepared and their electrochemical properties of sensing the various anions, the dependence of alkyl chain length, were investigated by voltammetry technologies. All of these ferrocenylimidazolium compounds were fully characterized by elemental analysis, NMR and mass spectrometry. Moreover, the structures of ferrocene-based methylimidazolium receptors 1a, 1b, 2b, and 3b were confirmed by X-ray crystallography. The ferrocenylimidazolium 1a and 2a receptors in which the ferrocene center and methylimidazolium fragments are directly linked showed redox waves for both the ferrocenyl moiety and the methylimidazolium moiety and exhibited rather strong electrochemical sensing properties for F- anion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.028
• 作为产物：
  描述：

  N-甲基咪唑 、 3‐chloropropylferrocene 反应 24.0h， 以57%的产率得到1-(ferrocenylpropyl)-3-methylimidazolium chloride
  参考文献：
  名称：

  Synthesis, characterization, and electrochemical properties of ferrocenylimidazolium

  摘要：

  A series of ferrocene-based methylimidazolium receptors were prepared and their electrochemical properties of sensing the various anions, the dependence of alkyl chain length, were investigated by voltammetry technologies. All of these ferrocenylimidazolium compounds were fully characterized by elemental analysis, NMR and mass spectrometry. Moreover, the structures of ferrocene-based methylimidazolium receptors 1a, 1b, 2b, and 3b were confirmed by X-ray crystallography. The ferrocenylimidazolium 1a and 2a receptors in which the ferrocene center and methylimidazolium fragments are directly linked showed redox waves for both the ferrocenyl moiety and the methylimidazolium moiety and exhibited rather strong electrochemical sensing properties for F- anion. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.12.028