[PdCl(C(O)CH3)(1,2-bis(diphenylphosphinomethyl)benzene)] | 937733-60-3

• 英文名称: [PdCl(C(O)CH3)(1,2-bis(diphenylphosphinomethyl)benzene)]
• CAS: 937733-60-3
• 化学式: C₃₄H₃₁ClOP₂Pd
• 分子量: 659.44
• InChiKey: JZJNAQOXUSDWSR-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [PdCl(CH3)(1,2-bis(diphenylphosphinomethyl)benzene)] 、 一氧化碳 以 氘代氯仿 为溶剂， 生成 [PdCl(C(O)CH3)(1,2-bis(diphenylphosphinomethyl)benzene)]
  参考文献：
  名称：

  High-pressure NMR study of migratory CO-insertion in palladium–methyl complexes modified with Cs-symmetrical 1,4-diphosphines

  摘要：

  Carbonylation of the palladium complexes [PdCH3((PP)-P-boolean AND')Cl] ((PP)-P-boolean AND'= 1a, 1b, 1c, 1d, 1e) and [PdCH3((PP)-P-boolean AND')(CH3CN)](OTf) was investigated by means of high-pressure NMR with the determination of the half-life times t(1/2). The results were rationalized on the basis of the electronic properties of the diphosphines and the nature of the solvento ligand in the first coordination sphere. The crystal structures of the complexes [Pd(1b)Cl-2] and [Pd(1b)(H2O)(2)](OTf)(2) are described (1b = 1-(diphenylphosphinomethyl)-2-[bis(3- trifluoromethylphenyl)phosphinomethyl]benzene). (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.01.020