[Rh(tetrasulfonated bis(diphenylphosphino)butane)(dimethylmaleate)][BF4] | 935755-11-6

• 英文名称: [Rh(tetrasulfonated bis(diphenylphosphino)butane)(dimethylmaleate)][BF4]
• 英文别名: [Rh(DPPBTS)(DMM)][BF4]
• CAS: 935755-11-6
• 化学式: BF₄*C₃₄H₃₆O₁₆P₂RhS₄
• 分子量: 1080.57
• InChiKey: CMBWDAMFDJAJGU-MECAPONASA-N

反应信息

• 作为产物：
  描述：

  [Rh(tetrasulfonated bis(diphenylphosphino)butane)(D2O)2][BF4] 、 马来酸二甲酯 以 not given 为溶剂， 生成 [Rh(tetrasulfonated bis(diphenylphosphino)butane)(dimethylmaleate)][BF4]
  参考文献：
  名称：

  Rhodium(I) hydrogenation in water: Kinetic studies and the detection of an intermediate using 13C{1H} PHIP NMR spectroscopy

  摘要：

  The mechanism for hydrogenation of dimethylmaleate in water using cationic rhodium complexes with water-soluble bi-dentate phosphines has been investigated using kinetics and a novel method for the indirect detection of intermediates in catalytic hydrogenation reactions, whereby a late intermediate was detected. A mechanism is proposed involving fast, irreversible substrate binding followed by a rate-determining reaction with dihydrogen. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.08.042