| 150393-49-0

• CAS: 150393-49-0
• 化学式: C₁₈H₁₄Cl₂N₄Ni
• 分子量: 415.932
• InChiKey: YCERAKVZVKACAO-MYHDMYFSSA-L

反应信息

• 作为反应物：
  描述：

  以 甲醇 、 水 为溶剂， 生成 bis-aquo-1,2-bis(2'-pyridylmethyleneimino)benzene nickel(II) dichloride
  参考文献：
  名称：

  Garoufis, Achilleas; Kasselouri, Spyridoula; Mitsopoulou, Christine-Anne, Polyhedron, 1999, vol. 18, p. 39 - 48

  摘要：

  DOI：
• 作为产物：
  描述：

  邻苯二胺 、 吡啶-2-甲醛 、 nickel(II) chloride hexahydrate 以 乙醇 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Coordination compounds of cobalt, nickel, copper, and zinc with N 1,N 2-bis(pyridin-2-ylmethylidene)benzene-1,2-diamine and its derivatives

  摘要：

  o-Phenylenediamine reacts with 2-formyl-, 2-acetyl-, or 2-benzoylpyridine in ethanol in the presence of cobalt, nickel, copper, or zinc chlorides to form monomeric complexes ML1-3Cl2 center dot nH(2)O {M = Co, Ni, Cu, Zn; L-1 = N (1),N (2)-bis(pyridin-2-ymethylidene)benzene-1,2-diamine, L-2 = N (1),N (2)-bis(pyridin-2-ylethylidene) benzene-1,2-diamine, L-3 = N (1),N (2)-bis[phenyl(pyridin-2-yl)methylidene]benzene-1,2-diamine; n = 0-3}. The condensation products (L-1-L-3) act in the complexes as tetradentate N,N,N,N-ligands. Thermolysis of the complexes occurs in two stages: dehydration (70-95A degrees C) and complete degradation (320-450A degrees C). At concentrations of 10(-5)-10(-7) M, the complexes inhibit in vitro growth and proliferation of HL-60 human promyelocytic leukemia cells.

  DOI：

  10.1134/s1070363214090217

文献信息

• Garoufis, Achilleas; Kasselouri, Spyridoula; Raptopoulou, Catherine P., Polyhedron, 1999, vol. 18, p. 585 - 592
  作者：Garoufis, Achilleas、Kasselouri, Spyridoula、Raptopoulou, Catherine P.、Terzis, Aris

  DOI：——

  日期：——