ferricenium boronic acid | 288101-87-1

• 英文名称: ferricenium boronic acid
• 英文别名: ferroceniun boronic acid
• CAS: 288101-87-1
• 化学式: C₁₀H₁₁BFeO₂
• 分子量: 229.854
• InChiKey: YBWANSBHSPBBQM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  ferrocene boronic acid 在 四丁基高氯酸铵 作用下， 生成 ferricenium boronic acid
  参考文献：
  名称：

  硼酸与四氟硼酸盐反应？这取决于酸度

  摘要：

  摘要 二茂铁硼酸经电化学或化学氧化后，得到的硼酸铁与四氟硼酸反应生成三氟硼酸铁。这种与普通电解质的反应可以扩展到其他具有足够低 pK a 的硼酸（

  DOI：

  10.1016/j.inoche.2014.08.031

文献信息

• Ferrocenylboronates: Crystal structures and electrochemical properties
  作者：Victor Barba、Norberto Farfán、Serena Losi、Piero Zanello

  DOI：10.1016/j.ica.2005.09.014

  日期：2006.3

  The electrochemical behavior of a series of eight previously reported monoferrocenyl- and diferrocenyl-boronates derived from tridentate ligands has been studied. Even if most mononuclear and all the dinuclear complexes examined showed to undergo slow decomposition in nonaqueous solution (releasing free ferrocenyl boronic acid), their redox activity has been investigated. It has been proved that the oxidation of the two ferrocenyl subunits in the dimeric species proceeds simultaneously,. indicating that no mutual electronic interaction exists between them. Additionally, the solid-state molecular structures of two diferrocenyl complexes (2a and 2b) were studied by X-ray diffraction. The analysis confirms the formation of a [5.4.0] heterobicycle with the presence of two different boron atoms, one in a tetrahedral geometry and the other one in a trigonal geometry. (c) 2005 Elsevier B.V. All rights reserved.
• Oxidation of ferrocenylboric acid with hydrogen peroxide in organic and aqueous media
  作者：V. M. Fomin、K. S. Zaitseva、A. A. Kozlova

  DOI：10.1134/s1070363214120123

  日期：2014.12

  Oxidation of ferrocenylboric acid with hydrogen peroxide in organic solvents and in aqueous solutions in the presence and in the absence of acids and bases has been investigated by electron absorption spectroscopy. Kinetics of FcB(OH)(2) oxidation in neutral, acidic, and basic media has been studied; possible mechanisms of the reactions accounting for the substituent acting as the Lewis-type acidic center have been suggested.