(η(5)-C5H5)2La(C3H5) | 182205-12-5

• 英文名称: (η(5)-C5H5)2La(C3H5)
• CAS: 182205-12-5
• 化学式: C₁₃H₁₅La
• 分子量: 310.168
• InChiKey: BSVNXCOFMASAIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 环戊二烯 以 氘代四氢呋喃 为溶剂， 生成 tricyclopentadienyllanthanum 、 (η(5)-C5H5)2La(C3H5) 、
  参考文献：
  名称：

  139La-NMR-spektroskopie an allyllanthan(III)-komplexen

  摘要：

  La-139-NMR chemical shifts were measured for several anionic complexes of formulae [Li(C4H8O2)(3/2)][La(eta(3)-C3H5)(4)], [Li(C4H8O2)(2)][Cp(n)'La(eta(3)-C3H5)(4-n)](Cp' = Cp(eta(5)-C5H5); n = 1, 2 and Cp' = Cp*(eta(5)-C(5)Me(5)); n = 1) and Li[R(n)La(eta(3)-C3H5)(4-n)] (R = N(SiMe(3))(2); n = 1, 2 and R = C=CSiMe(3); n = 4), as well as for neutral compounds of formulae La(eta(3)-C3H5)(3)L(n) (L(n) = (C4H8O2)(1.5), (HMPT)(2), TMED), Cp(n)'La(eta(3)-C3H5)(3-n) (Cp' = Cp(eta(5)-C5H5), Cp*(eta(5)-C(5)Me(5)); n = 1, 2) and La(eta(3)-C3H5)(2)X(THF)(2) (X = Cl, Br, I). Typical ranges of the La-139-NMR chemical shifts were found for the different types of complex independent of number and kind of organyl groups directly bonded to lanthanum.

  DOI：

  10.1016/0022-328x(96)06259-6