| 1581713-78-1

• CAS: 1581713-78-1
• 化学式: C₃₄H₂₃Cl₂F₆N₂O₂Pd₂Se₂
• 分子量: 1047.23
• InChiKey: YDHHOUVDYRRKBM-BYNBHZIPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 二苯基乙炔 以 甲苯 为溶剂， 反应 12.0h， 以67%的产率得到2-(2-methoxyphenyl)-3,4-diphenylbenzo[4,5]selenopheno[2,3-c]pyridin-1(2H)-one
  参考文献：
  名称：

  Intramolecular heterocyclization and cyclopalladation of selenoanisole substituted propargyl imines: Synthesis and reactivity of Pd–C bond towards alkynes

  摘要：

  The intramolecular cyclization of o-SeMeC6H4C CC-(CF3)(=NAr) with [PdCl2(PhCN)(2)] to dimeric cyclopalladated benzoselenophene has been developed under mild conditions. The reactivity of the new dimeric cyclopalladated benzoselenophene is examined towards insertion of alkynes into Pd-C bond. The reactivity study is also extended to Pd-C bond of dimeric cyclopalladated benzothiophenes towards insertion of alkynes. (C) 2014 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2014.01.028
• 作为产物：
  描述：

  (2-(4-(2-methoxyphenyl)-3-(trifluoromethyl)but-3-en-1-ynyl)phenyl)(methyl)selane 、 [PdCl₂(PhCN)₂] 以 四氢呋喃 为溶剂， 反应 2.0h， 以82%的产率得到
  参考文献：
  名称：

  Intramolecular heterocyclization and cyclopalladation of selenoanisole substituted propargyl imines: Synthesis and reactivity of Pd–C bond towards alkynes

  摘要：

  The intramolecular cyclization of o-SeMeC6H4C CC-(CF3)(=NAr) with [PdCl2(PhCN)(2)] to dimeric cyclopalladated benzoselenophene has been developed under mild conditions. The reactivity of the new dimeric cyclopalladated benzoselenophene is examined towards insertion of alkynes into Pd-C bond. The reactivity study is also extended to Pd-C bond of dimeric cyclopalladated benzothiophenes towards insertion of alkynes. (C) 2014 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2014.01.028