[Pt(3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl)benzylamino]ethylindole-H)Cl] | 1137151-83-7

• 英文名称: [Pt(3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl)benzylamino]ethylindole-H)Cl]
• CAS: 1137151-83-7
• 化学式: C₃₁H₃₈ClN₃OPt
• 分子量: 699.195
• InChiKey: AAHBAZSBNMBAFI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl)benzylamino]ethylindole-H)Cl] 在 Ce(IV) 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 [Pt(3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl)benzylamino]ethylindole-H)Cl](1+)
  参考文献：
  名称：

  Synthesis and characterization of platinum(II) complexes of 2N1O-donor ligands with a pendent indole ring

  摘要：

  The Pt(II) complexes of 2N1O-donor ligands containing a pendent indole, 3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl) benzylamino] ethylindole (Htbu-iepp), and 1-methyl-3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl) benzylamino] ethylindole (Htbu-miepp) (H denotes an ionizable hydrogen), were synthesized, and the structure of [Pt(tbu-iepp) Cl] (1) was determined by X-ray analysis. Complex 1 prepared in CH3CN was revealed to have the C2 atom of the indole ring bound to Pt(II) with the Pt(II)-C2 distance of 1.981(3) angstrom. On the other hand, [Pt(tbu-miepp) Cl] (2) was concluded to have a phenolate coordination instead of the C2 atom of the indole ring by H-1 NMR spectra. Reaction of 1 with 1 equiv. of Ce(IV) in DMF gave the corresponding one-electron oxidized species, which exhibited an ESR signal at g = 2.004 and an absorption peak at 567 nm, indicating the formation of the Pt(II)-indole-pi-cation radical species. The half-life, t(1/2), of the radical species at -60 degrees C was calculated to be 43 s (k(obs) = 1.6 x 10(-2) s(-1)). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.01.046
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 3-[N-2-pyridymethyl-N-2-hydroxy-3,5-di(tert-butyl)benzylamino]ethylindole 以 水 、 乙腈 为溶剂， 生成 [Pt(3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl)benzylamino]ethylindole-H)Cl]
  参考文献：
  名称：

  Synthesis and characterization of platinum(II) complexes of 2N1O-donor ligands with a pendent indole ring

  摘要：

  The Pt(II) complexes of 2N1O-donor ligands containing a pendent indole, 3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl) benzylamino] ethylindole (Htbu-iepp), and 1-methyl-3-[N-2-pyridylmethyl-N-2-hydroxy-3,5-di(tert-butyl) benzylamino] ethylindole (Htbu-miepp) (H denotes an ionizable hydrogen), were synthesized, and the structure of [Pt(tbu-iepp) Cl] (1) was determined by X-ray analysis. Complex 1 prepared in CH3CN was revealed to have the C2 atom of the indole ring bound to Pt(II) with the Pt(II)-C2 distance of 1.981(3) angstrom. On the other hand, [Pt(tbu-miepp) Cl] (2) was concluded to have a phenolate coordination instead of the C2 atom of the indole ring by H-1 NMR spectra. Reaction of 1 with 1 equiv. of Ce(IV) in DMF gave the corresponding one-electron oxidized species, which exhibited an ESR signal at g = 2.004 and an absorption peak at 567 nm, indicating the formation of the Pt(II)-indole-pi-cation radical species. The half-life, t(1/2), of the radical species at -60 degrees C was calculated to be 43 s (k(obs) = 1.6 x 10(-2) s(-1)). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.01.046