Halo-, hydrido- and dinitrogen-complexes of iron(II) with tritertiary phosphines
作者:P. Stoppioni、F. Mani、L. Sacconi
DOI:10.1016/s0020-1693(00)93713-7
日期:1974.1
Abstract From the five-coordinate iron(II) complexes [FeXL] BPh 4 , (L = tris(2-diphenylphosphinoethyl)amine, np 3 , and tris(2-diphenylphosphinoethyl)phosphine, pp 3 ) hydrido and hydridodinitrogencomplexes have been obtained; these have formula [FeH(pp 3 )]BPh 4 and [FeHN 2 L]BPh 4 (L = np 3 , PP 3 . In the latter complexes the dinitrogen molecule may be replaced by other neutral ligands such as