[Rh(CO)2(PhB(C6H4PPh2)2)]SbF6 | 1315572-97-4

• 英文名称: [Rh(CO)2(PhB(C6H4PPh2)2)]SbF6
• CAS: 1315572-97-4
• 化学式: C₄₄H₃₃BO₂P₂Rh*F₆Sb
• 分子量: 1005.15
• InChiKey: YKWVAAMNNHSECG-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Rh(CO)2(PhB(C6H4PPh2)2)]SbF6 、 乙腈 以 乙腈 为溶剂， 以88%的产率得到[Rh(MeCN)2(PhB(C6H4PPh2)2)]SbF6
  参考文献：
  名称：

  Lewis Acids and Lewis Acid-Functionalized Ligands in Rhodium-Catalyzed Methyl Acetate Carbonylation

  摘要：

  The application of Lewis acids and Lewis acid-functionalized ligands as activators for methyl acetate in the rhodium-catalyzed carbonylation of methyl acetate to acetic anhydride has been investigated. The reaction of methyl acetate with B(C6F5)(3) results in the formation of the adduct [MeOAc center dot B(C6F5)(3)]. The combination of this adduct with [Rh(OAc)-(CO)(2)](2) results in a transfer of the Lewis acid to the rhodium complex, rather than an anticipated oxidative addition reaction. In a second approach, novel Lewis acid-functionalized rhodium-(I) complexes [Rh(CO)Cl(BPP)], [Rh(CO)(2)(EPP)]SbF6, and [Rh(MeCN)(2)(BPP)]SbF6 (BPP = PhB(C6H4PPh2)(2)) have been prepared. The lack of reactivity of [Rh(CO)(2)(BPP)]SbF6 toward MeOAc has shown that the rhodium boron interaction is too strong for activation of methyl acetate, and no carbonylation activity was observed under the conditions used.

  DOI：

  10.1021/om200341t
• 作为产物：
  描述：

  silver hexafluoroantimonate 、 一氧化碳 、 [Rh(CO)Cl(PhB(C6H4PPh2)2)] 以 氯仿 为溶剂， 以61%的产率得到[Rh(CO)2(PhB(C6H4PPh2)2)]SbF6
  参考文献：
  名称：

  Lewis Acids and Lewis Acid-Functionalized Ligands in Rhodium-Catalyzed Methyl Acetate Carbonylation

  摘要：

  The application of Lewis acids and Lewis acid-functionalized ligands as activators for methyl acetate in the rhodium-catalyzed carbonylation of methyl acetate to acetic anhydride has been investigated. The reaction of methyl acetate with B(C6F5)(3) results in the formation of the adduct [MeOAc center dot B(C6F5)(3)]. The combination of this adduct with [Rh(OAc)-(CO)(2)](2) results in a transfer of the Lewis acid to the rhodium complex, rather than an anticipated oxidative addition reaction. In a second approach, novel Lewis acid-functionalized rhodium-(I) complexes [Rh(CO)Cl(BPP)], [Rh(CO)(2)(EPP)]SbF6, and [Rh(MeCN)(2)(BPP)]SbF6 (BPP = PhB(C6H4PPh2)(2)) have been prepared. The lack of reactivity of [Rh(CO)(2)(BPP)]SbF6 toward MeOAc has shown that the rhodium boron interaction is too strong for activation of methyl acetate, and no carbonylation activity was observed under the conditions used.

  DOI：

  10.1021/om200341t