Rh(I)(O3S(C6H4)CH2C(CH2P(C6H5)2)3)(CO)2 | 172221-18-0

• 英文名称: Rh(I)(O3S(C6H4)CH2C(CH2P(C6H5)2)3)(CO)2
• 英文别名: (O3SC6H4CH2C(CH2PPh2)3)Rh(CO)2
• CAS: 172221-18-0
• 化学式: C₄₉H₄₂O₅P₃RhS
• 分子量: 938.762
• InChiKey: PBRDWPKJXOTFQS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 Na(O3SC6H4CH2C(CH2PPh2)3) 生成 Rh(I)(O3S(C6H4)CH2C(CH2P(C6H5)2)3)(CO)2
  参考文献：
  名称：

  Zwitterionic Metal Complexes of the New Triphosphine NaO3S(C6H4)CH2C(CH2PPh2)3 in Liquid Biphasic Catalysis: An Alternative to Teflon "Ponytails" for Facile Catalyst Separation without Water

  摘要：

  The new Ligand NaO3S(C6H4)CH2C(CH(2)PPh(2))(3) (sulphos) has been synthesized. The application of the zwitterionic Rh(I) complexes (sulphos)Rh(cod) and (sulphos)Rh(CO)(2) in liquid biphasic catalysts has been demonstrated for the hydrogenation of styrene and the hydroformylation of 1-hexene, respectively. The Latter reaction gives C-7 alcohols in an alcohol/hydrocarbon system and C-7 aldehydes in an alcohol-water/hydrocarbon system. All rhodium a's recovered in the polar phase at the end of the catalytic reactions.

  DOI：

  10.1021/om00012a002